Scientists at Stanford University and the Department of Energy’s SLAC National Accelerator Laboratory have a one-pot synthesis process using diamondoids—the smallest possible bits of diamond—to assemble atoms into hybrid metal–organic chalcogenide nanowires with solid inorganic cores having three-atom cross-sections, representing the smallest possible nanowires.
By grabbing various types of atoms and putting them together LEGO-style, the new technique could potentially be used to build tiny wires for a wide range of applications, including fabrics that generate electricity, optoelectronic devices that employ both electricity and light, and superconducting materials that conduct electricity without any loss. The scientists reported their results in Nature Materials.
|Schematic of synthesis and structure of metal– organic chalcogenides (MOCs) crystals. a, Schematic of the two-phase synthetic strategy for MOC crystals. R, adamantane or diamantane; M, Cu; EG, ethylene glycol. b, Refined SC-XRD structure of copper adamantane-1-thiolate (1ADCu) viewed along the chain elongation direction. Cu, S and C are represented by brown, yellow and black colors, respectively. The blue spheres denote the vdW radii of the adamantane side group. Yan et al. Click to enlarge.|
What we have shown here is that we can make tiny, conductive wires of the smallest possible size that essentially assemble themselves. The process is a simple, one-pot synthesis. You dump the ingredients together and you can get results in half an hour. It’s almost as if the diamondoids know where they want to go.—Hao Yan, a Stanford postdoctoral researcher and lead author of the paper
Although there are other ways to get materials to self-assemble, this is the first one shown to make a nanowire with a solid, crystalline core that has good electronic properties, said study co-author Nicholas Melosh, an associate professor at SLAC and Stanford and investigator with SIMES, the Stanford Institute for Materials and Energy Sciences at SLAC.
The needle-like wires have a semiconducting core—a combination of copper and sulfur known as a chalcogenide—surrounded by the attached diamondoids, which form an insulating shell.
Their minuscule size is important, Melosh said, because a material that exists in just one or two dimensions—as atomic-scale dots, wires or sheets—can have very different, extraordinary properties compared to the same material made in bulk. The new method allows researchers to assemble those materials with atom-by-atom precision and control.
The diamondoids they used as assembly tools are tiny, interlocking cages of carbon and hydrogen. Found naturally in petroleum fluids, they are extracted and separated by size and geometry in a SLAC laboratory. Over the past decade, a SIMES research program led by Melosh and SLAC/Stanford Professor Zhi-Xun Shen has found a number of potential uses for the little diamonds, including improving electron microscope images and making tiny electronic gadgets.
For this study, the research team took advantage of the fact that diamondoids are strongly attracted to each other through van der Waals forces. (This attraction is what makes the microscopic diamondoids clump together into sugar-like crystals, which is the only reason you can see them with the naked eye.)
They started with the smallest possible diamondoids—single cages that contain just 10 carbon atoms—and attached a sulfur atom to each. Floating in a solution, each sulfur atom bonded with a single copper ion. This created the basic nanowire building block.
The building blocks then drifted toward each other, drawn by the van der Waals attraction between the diamondoids, and attached to the growing tip of the nanowire.
Much like LEGO blocks, they only fit together in certain ways that are determined by their size and shape. The copper and sulfur atoms of each building block wound up in the middle, forming the conductive core of the wire, and the bulkier diamondoids wound up on the outside, forming the insulating shell.—Stanford graduate student Fei Hua Li
The team has already used diamondoids to make one-dimensional nanowires based on cadmium, zinc, iron and silver, including some that grew long enough to see without a microscope, and they have experimented with carrying out the reactions in different solvents and with other types of rigid, cage-like molecules, such as carboranes.
The cadmium-based wires are similar to materials used in optoelectronics, such as light-emitting diodes (LEDs), and the zinc-based ones are like those used in solar applications and in piezoelectric energy generators, which convert motion into electricity.
You can imagine weaving those into fabrics to generate energy. This method gives us a versatile toolkit where we can tinker with a number of ingredients and experimental conditions to create new materials with finely tuned electronic properties and interesting physics.—Nicholas Melosh
Theorists led by SIMES Director Thomas Devereaux modeled and predicted the electronic properties of the nanowires, which were examined with X-rays at SLAC’s Stanford Synchrotron Radiation Lightsource, a DOE Office of Science User Facility, to determine their structure and other characteristics.
The team also included researchers from the Stanford Department of Materials Science and Engineering, Lawrence Berkeley National Laboratory, the National Autonomous University of Mexico (UNAM) and Justus-Liebig University in Germany. Parts of the research were carried out at Berkeley Lab’s Advanced Light Source (ALS) and National Energy Research Scientific Computing Center (NERSC), both DOE Office of Science User Facilities. The work was funded by the DOE Office of Science and the German Research Foundation.
Hao Yan, J. Nathan Hohman, Fei Hua Li, Chunjing Jia, Diego Solis-Ibarra, Bin Wu, Jeremy E. P. Dahl, Robert M. K. Carlson, Boryslav A. Tkachenko, Andrey A. Fokin, Peter R. Schreiner, Arturas Vailionis, Taeho Roy Kim, Thomas P. Devereaux, Zhi-Xun Shen & Nicholas A. Melosh (2016) “Hybrid metal–organic chalcogenide nanowires with electrically conductive inorganic core through diamondoid-directed assembly” Nature Materials doi: